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By W.A. E. McBryde

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Additional info for A Critical Review of Equilibrium Data for Proton and Metal Complexes of 1,10–phenanthroline, 2,2'–Bipyridyl and Related Compounds. Critical Evaluation of Equilibrium Constants in Solution: Stability Constants of Metal Complexes

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3% aq. 4% aq. 0% aq. 1% aq. 7% aq. 0% aq. 6% aq. 2 Temp. PKi Temp. 34 20 20% aq. 62 25 50% aq. 47 25 50% aq. 41 25 50% aq. 58 25 50% aq. 94 25 75% aq. 40 25 50% aq. 97 25 50% aq. l (Continued) Substituent Unsubstituted pKi Method Reference 25 25% aq. n-PrOH 50% aq. n-PrOH 75% aq. 58 25 25% aq. Me 2 CO 50% aq. M e 2 C 0 75% aq. 2 7 ON 25 25 25 25 25 25 25 25 25 25 Aq. 001 I 8% aq. 4% aq. 3% aq. 4% aq. 0% aq. 1% aq. 7% aq. 0% aq. 6% aq. 2 Temp. PKi Temp. 34 20 20% aq. 62 25 50% aq. 47 25 50% aq. 41 25 50% aq.

S / -N Tj ■M G •H O O v-^ M rH o 00 00 O « TJ £ S &o dJ o H Ö O L O vO O vD U vO 00 U vO CO o • o σ\• o CO ON O O O 1 ^ 1 O vD O ^ CN 00 00 V D v£> rH σ\• O O ΟΛ V D rH ™ < Q U rH io LO CN m IO vO rH LO m LO O LO LO pq σ> LO v£> LO Fu

54 25 75% aq. 65 25 50% aq. 40 25 50% aq. 00 25 50% aq. 30 25 50% aq. 43 25 50% aq. 30 25 50% aq. 10 - 50% aq. 43 25 50% aq. 65 25 50% aq. 80 25 50% aq. 23 50% aq. 13 25 25% aq. MeOH 50% aq. MeOH 75% aq. 73 25 25% aq. EtOH 50% aq. EtOH 75% aq. l (Continued) Substituent Unsubstituted pKi Method Reference 25 25% aq. n-PrOH 50% aq. n-PrOH 75% aq. 58 25 25% aq. Me 2 CO 50% aq. M e 2 C 0 75% aq. 2 7 ON 25 25 25 25 25 25 25 25 25 25 Aq. 001 I 8% aq. 4% aq. 3% aq. 4% aq. 0% aq. 1% aq. 7% aq. 0% aq. 6% aq.

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