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80 D. O t h e r - S t u a i e s continued on t h e measurement o f p h y s i c a l chemical parameters o e l f i d a t e s t r u c t u r e a c t i v i r y p a t t e r n s i n psychotomimetic compounds. Thus X-ray, in ordlif-’ nu& and t o t a l o r b i t a l e n e r g i e s a 4 were used t o study molecular conformation and i t s r e l a t i o n s h i p t o psychotonimetic a c t i v i t y i n t h e l y s e r g i c a c i d series. The conformations o f p s i l o c i n and mescalice we85 examined by molecular o r b i t a l and c l a s s i c a l p o t e n t i a l function calculations C o r r e l a t i o n s o f uv s p e c t r a , ‘6 n a t i v e fluorescence87 and a s s o c i a t i o n constants*8 with t h e psychotomimetic a c t i v i t y of v a r i o u s methoxylated phenylisopropylanines were made.

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Rowe, Science, 177. 62 (1972). L. Lemberger, N. Tanurkin, J. Axelrod, and 1. Kopin, Science, 173. 72 (1971). L. Lemberger, J. Weiss, A. Watanabe, I. G a l a n t e r , R Wyatt, a n d P. Cardon, New Eng. J. Med. 286. 685 (1972). M. Wall, D. Brine, C. P i t t , M. Perez-Reyes, J. h e r . Chem. , & 8579 (1972). K. Weinhardt, R. Razdan, and H. D a l z e l l b T e t r a h e d r o n L e t t . , 4827 (1971). J. Nilsson, I. Nilsson, S. A g u r e l l , B. Akenmrk a n d I. Lagerlund, Acta Chem. , 2 768 (1971).

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